German · Pronunciation Guide
dee TOKH-tuh. The ch is the throaty one after o, and the -er ending softens to 'uh'.
The first syllable carries it and the second trails off. The plural Töchter fronts the vowel to a short ö, and — as with Nacht and Nächte — that fronting also flips the ch from the throaty variant to the soft one, since the sound follows the vowel rather than the spelling.
Listen: die Tochter
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Seine Tochter studiert Medizin.
His daughter studies medicine.
Listen: Seine Tochter studiert Medizin.
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Seine Tochter studiert Medizin contains two borrowings with back-stress: studiert puts its beat on the -iert ending, which is what every -ieren verb does, and Medizin stresses its final syllable. Studiert also opens on the 'sht' cluster.
Substituting a k for the ch gives 'TOK-ter', which loses the word's most German feature and adds an English r on top. Fix both. Then note the plural: Töchter takes the soft hiss, so a learner who has just drilled the throaty ch in the singular has to unlearn it for the plural.