German · Pronunciation Guide
ZEE. A voiced s at the front and a long 'ee' from ie.
Unstressed in almost every sentence, which creates a practical difficulty: sie meaning she, sie meaning they, and the capitalised Sie meaning formal you are pronounced identically, and none of them gets extra emphasis to help you. The verb ending does the disambiguating instead, so the word after this one is the one to listen to.
Listen: sie
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Sie spricht gut Deutsch.
She speaks German well.
Listen: Sie spricht gut Deutsch.
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Sie spricht gut Deutsch settles the ambiguity through the verb: spricht is a third-person singular form with its stem vowel changed from e to i, so this can only be she. Were it they or formal you, the verb would be sprechen. Deutsch ends in the ch of church, giving 'doytch'.
A hissed s produces 'see', which is the default English reading and wrong in the one consonant the word has. It buzzes. Beyond the sound, the three-way overlap is genuinely hard, and learners often try to solve it by stressing the pronoun differently — that does not work in German. Train yourself to take the answer from the verb ending.