French · Pronunciation Guide
plan — one nasal syllable, where "-ein" is the same vowel as in "pain" and "main", not "ayn".
One nasal syllable. The feminine "pleine" is /plɛn/, with a real "n" and no nasalization — so the two forms sound distinctly different even though they look almost identical.
Listen: plein
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Le train est plein.
The train is full.
Listen: Le train est plein.
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"Le train est plein" ends on the adjective, so the nasal vowel gets its full length. Notice the sentence contains two nasal vowels of different kinds: "train" and "plein" happen to share /ɛ̃/, giving the phrase an internal rhyme. "Est" between them is just /ɛ/, a bare open vowel.
Learners read "-ein" as they would in English "vein" or "rein", giving "playn". It is a nasal, and the tongue must never touch. The other slip is the feminine: "pleine" un-nasalizes completely, so applying the masculine sound to a feminine noun is audibly wrong. Note also the idiom "faire le plein", which means to fill up with fuel.