Spanish · Pronunciation Guide
syen, one syllable, opening with an s sound — not a k, and not two beats.
Only one syllable, so the stress rule has nothing to choose between. Worth knowing that "cien" is the shortened form used directly before a noun; the full "ciento" adds a syllable and stresses CIEN-to, second-to-last, per the usual rule. Neither form takes an accent.
Listen: cien
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El libro cuesta cien pesos.
The book costs a hundred pesos.
Listen: El libro cuesta cien pesos.
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"El libro cuesta cien pesos" uses the short form because a noun follows immediately — say "ciento" here and it sounds wrong to a native ear. "Cuesta" opens with the same hard-c-plus-glide you met in "cuatro", KWEHS-ta, and gives a nice contrast within one sentence: the c in "cuesta" is a k, the c in "cien" is an s, decided purely by the vowel that follows.
English speakers reading this cold often produce "kyen" or "see-EN". Both halves need fixing: the c is soft because an e follows it, and the ie is a single glide rather than two vowels. There is also a meaning trap worth flagging — "cien" is exactly one hundred, while "cientos" means hundreds, and mixing them up in a shop is more expensive than mispronouncing either.