Hindi · Pronunciation Guide
shaam with a long open aa — like English "shalom" without the l, and much longer than "sham."
shaam
Because it is often followed by the postposition ko, English rhythm wants to compress the noun into the next word. Resist that — the long vowel is its only distinguishing feature.
Listen: शाम
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शाम को मैं घर पर रहता हूँ।
Shaam ko maiṁ ghar par rehtaa hooṁ.
In the evening I am at home.
Listen: शाम को मैं घर पर रहता हूँ।
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"Shaam ko maiṁ ghar par rehtaa hooṁ" attaches ko to the time expression, which is how Hindi marks "in the evening." Ghar's breathy-voiced घ then arrives a few syllables later, so the sentence sets a plain fricative against a breathy stop.
The vowel is the whole battle: English speakers produce the short vowel of "sham," which is a completely different length. Stretch it to the duration of "calm." The m at the end is straightforward, so all your attention can go to the vowel.