Portuguese (Brazil) · Pronunciation Guide
ah peh-SOH-ah. The double s is one plain hiss, and the word ends in two separate vowels.
The "sso" is the second-to-last syllable and therefore the loud one. The final two vowels stay separate rather than forming a diphthong, because Portuguese only builds diphthongs around an unstressed i or u — an o and an a side by side always split into two beats.
Listen: a pessoa
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Ela é uma boa pessoa.
She is a good person.
Listen: Ela é uma boa pessoa.
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"Ela é uma boa pessoa" links four vowel-heavy words in a row, and Brazilians glide straight through: "ela é uma" comes out as one continuous stream. "Boa" is itself two syllables for the same reason "pessoa" ends in two — o and a never fuse.
Lengthening the double s is the phonetic slip; squashing the ending into a diphthong is the rhythmic one. There's also a grammar quirk worth knowing: "pessoa" is grammatically feminine regardless of who it describes, so a man is still "uma pessoa muito simpática" with feminine agreement throughout.