Portuguese (Brazil) · Pronunciation Guide
oo KAH-hoo. The double rr is a throaty h, not a rolled Spanish rr.
The default puts the weight on "ca-," as it does for any word ending in -o, and no accent is needed. The doubling of the r is a spelling device rather than a lengthening instruction: Portuguese uses rr between vowels to signal the throaty sound, because a single r there would be a light tap instead — which is exactly what separates "carro" from "caro."
Listen: o carro
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Vou de carro para o trabalho.
I drive to work.
Listen: Vou de carro para o trabalho.
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"Vou de carro para o trabalho" uses "de" for means of transport, pronounced "djee." In speech "para o" would fuse into "pro," giving "vou de carro pro trabalho" — and "trabalho" ends on an lh, so the sentence pairs a guttural with a palatal.
The rolled rr is the reflex for anyone with Spanish behind them, and it turns the word into something a Brazilian would find distinctly foreign. It's an h. The caro/carro pair is the practical stake: one tap means expensive, the throat-h means car, and the vowels are identical.