Portuguese (Brazil) · Pronunciation Guide
OH-troo. The ou at the front is a plain "oh" — there's no "oo" hiding after it.
The "ou" is loud, and it counts as a single syllable despite the two letters. It's a good word for testing the raising rule, since the first o is stressed and stays "oh" while the last is unstressed and lifts to "oo" — the two ends of the word show both halves of the pattern at once.
Listen: outro
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Quero outro café.
I want another coffee.
Listen: Quero outro café.
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"Quero outro café" links "quero outro" so the final "oo" of the verb runs straight into the "oh" of the adjective with no break. "Quero" itself has a silent u after the q, which is a nice counterpoint: one word where a written u disappears, followed by one where a written u has already merged into the vowel before it.
Pronouncing "ou" as "oo" gives "OO-troh," which gets the first vowel wrong and leaves the last one unraised. English speakers also break the tr cluster with an inserted vowel. On grammar: "outro" never takes an indefinite article, so "um outro café" is redundant — "outro café" is what you want.