Portuguese (Brazil) · Pronunciation Guide
pree-MAY-roo. Two r's, both taps, and an "ei" diphthong carrying the stress.
Three syllables, and the middle one is loud, which the -o default supplies without an accent. Note that the diphthong "ei" counts as one syllable for stress purposes, so the split is pri-mei-ro rather than pri-me-i-ro; if the i were meant to stand alone, Portuguese would mark it with an accent as it does in "país."
Listen: primeiro
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Este é meu primeiro emprego.
This is my first job.
Listen: Este é meu primeiro emprego.
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"Este é meu primeiro emprego" ends with "emprego," whose first syllable is nasal — the m before a p signals nasalization, exactly as in "importante." The adjective comes before the noun here, which is standard for ordinals and changes nothing about the stress.
Breaking the diphthong into "pri-meh-EE-roh" gives four syllables where there are three. Keep "ei" as one glide. Both r's also attract rolling from Spanish speakers, when they should be single taps. And note the shortened form: Brazilians write "1º" and say "primeiro," and the feminine "primeira" is used just as often.