Portuguese (Brazil) · Pronunciation Guide
seem-PAH-tchee-koo. Nasal first syllable, accent on the second, and a "tchee" in the third.
Another proparoxytone, stressed three syllables from the end, and like every one of them it must carry a written accent — Portuguese has no default rule that reaches that far back. Compare "último" and "médico," which are marked for exactly the same reason.
Listen: simpático
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Seu amigo é muito simpático.
Your friend is very friendly.
Listen: Seu amigo é muito simpático.
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"Seu amigo é muito simpático" links "seu amigo" across the word boundary so the w-glide of "seu" runs into the a of "amigo." The adjective agrees with the masculine noun, and it would become "simpática" for a woman without the stress moving at all.
The middle t is the Brazilian giveaway: "sim-PAH-tee-koh" keeps it hard and misses the change to "tch." Spanish speakers have "simpático" spelled identically, which makes the transfer nearly irresistible and wrong on that one consonant plus the final vowel. And it's a false friend for English speakers, since it means friendly rather than sympathetic.